Voltammetric Determination of Herbicide Biphenox on Mercury-Meniscus-Modified Solid Silver Amalgam Electrode

Authors

  • D. Cabalková Department of Analytical Chemistry, UNESCO Laboratory of Environmental Electrochemistry, Charles University, Prague,
  • J. Barek Department of Analytical Chemistry, UNESCO Laboratory of Environmental Electrochemistry, Charles University, Prague,
  • J. Fischer Department of Analytical Chemistry, UNESCO Laboratory of Environmental Electrochemistry, Charles University, Prague,
  • T. Navrátil J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Prague
  • K. Pecková Department of Analytical Chemistry, UNESCO Laboratory of Environmental Electrochemistry, Charles University, Prague,
  • B. Yosypchuk J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Prague

Abstract

Optimum conditions are described for the determination of micromolar and submicromolar concentrations of herbicide Biphenox by differential pulse voltammetry (DPV) on non-toxic solid silver amalgam electrode modified with mercury meniscus in aqueous methanol¬ic (9:1) Britton-Robinson buffer (pH 7). The limit of quantification is 2.4?10????????????7 mol l????????????1. Cyclic voltammetry with the same working electrode was used to clarify the mechanism of the electrode reaction.

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Published

2009-04-15

How to Cite

Cabalková, D., Barek, J., Fischer, J., Navrátil, T., Pecková, K., & Yosypchuk, B. (2009). Voltammetric Determination of Herbicide Biphenox on Mercury-Meniscus-Modified Solid Silver Amalgam Electrode. Chemické Listy, 103(3). Retrieved from http://blog.chemicke-listy.cz/ojs3/index.php/chemicke-listy/article/view/1564

Issue

Vol. 103 No. 3 (2009)

Section

Articles