Cluster Borane Analogues of Cyclopentadienyl Anion and Ferrocene

Authors

  • B. Štíbr Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic, Řež
  • B. Grüner Institute of Inorganic Chemistry, Academy of Sciences of the Czech Republic, Řež

Abstract

A review on cluster borane analogues of the cyclopentadienyl anion (Cp) and ferrocene is presented. The analogues of Cp are the eleven-vertex triheteroboranes of general structure [nido-E3B8H8]- (E is CH or CH and P) were used as effective ligands for the preparation of half- and full-sandwich complexes [CpFeE3B8H8] and [Fe(C3B8H10-NR2)2] (R is H or alkyl) – analogues of ferrocene. Advances in the area of phosphadicarbollides, diphosphacarbollides, and their iron complexes are discussed.

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Published

2006-07-15

How to Cite

Štíbr, B., & Grüner, B. (2006). Cluster Borane Analogues of Cyclopentadienyl Anion and Ferrocene. Chemické Listy, 100(6). Retrieved from http://blog.chemicke-listy.cz/ojs3/index.php/chemicke-listy/article/view/1921

Issue

Vol. 100 No. 6 (2006)

Section

Articles